A High Mobility P-Type DPP-Thieno[3,2-b]thiophene Copolymer for Organic Thin-Film Transistors

被引:512
作者
Li, Yuning [1 ,2 ]
Singh, Samarendra P. [1 ]
Sonar, Prashant [1 ]
机构
[1] ASTAR, IMRE, Singapore 117602, Singapore
[2] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
关键词
POLYMER SEMICONDUCTORS; PERFORMANCE; BANDGAP;
D O I
10.1002/adma.201002313
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A copolymer comprising 1,4-diketopyrrolo [3,4-c]pyrrole (DPP) and thieno[3,2-b]thiophene moieties, PDBT-co-TT, shows high hole mobility of up to 0.94 cm(2) V-1 s(-1) in organic thin-film transistors. The strong intermolecular interactions originated from pi-pi stacking and donor-acceptor interaction lead to the formation of interconnected polymer networks having an ordered lamellar structure, which have established highly efficient pathways for charge carrier transport.
引用
收藏
页码:4862 / +
页数:6
相关论文
共 35 条
[1]  
[Anonymous], ANGEW CHEM INT ED
[2]   Red electroluminescence from a 1,4-diketopyrrolo[3,4-c]pyrrole (DPP)-based conjugated polymer [J].
Beyerlein, T ;
Tieke, B ;
Forero-Lenger, S ;
Brütting, W .
SYNTHETIC METALS, 2002, 130 (02) :115-119
[3]   Poly(diketopyrrolopyrrole-terthiophene) for Ambipolar Logic and Photovoltaics [J].
Bijleveld, Johan C. ;
Zoombelt, Arjan P. ;
Mathijssen, Simon G. J. ;
Wienk, Martijn M. ;
Turbiez, Mathieu ;
de Leeuw, Dago M. ;
Janssen, Rene A. J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (46) :16616-+
[4]   High-mobility ambipolar near-infrared light-emitting polymer field-effect transistors [J].
Buergi, Lukas ;
Turbiez, Mathieu ;
Pfeiffer, Reto ;
Bienewald, Frank ;
Kirner, Hans-Joerg ;
Winnewisser, Carsten .
ADVANCED MATERIALS, 2008, 20 (11) :2217-2224
[5]   Diketopyrrolopyrrole-containing polyfluorenes: Facile method to tune emission color and improve electron affinity [J].
Cao, Derong ;
Liu, Qilin ;
Zeng, Wenjing ;
Han, Shaohu ;
Peng, Junbiao ;
Liu, Shouping .
MACROMOLECULES, 2006, 39 (24) :8347-8355
[6]   Improved mobility of amorphous silicon thin-film transistors deposited by hot-wire chemical vapor deposition on glass substrates [J].
Chu, V ;
Jarego, J ;
Silva, H ;
Silva, T ;
Reissner, M ;
Brogueira, P ;
Conde, JP .
APPLIED PHYSICS LETTERS, 1997, 70 (20) :2714-2716
[7]  
Conwell E., 1997, PRIMARY PHOTOEXCITAT
[8]   Relationship between the ionization and oxidation potentials of molecular organic semiconductors [J].
D'Andrade, BW ;
Datta, S ;
Forrest, SR ;
Djurovich, P ;
Polikarpov, E ;
Thompson, ME .
ORGANIC ELECTRONICS, 2005, 6 (01) :11-20
[9]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[10]  
2-9