One template, multiple rings: Controlled iterative addition of macrocycles onto a single binding site rotaxane thread

被引：72

作者：

Fuller, Anne-Marie L. ^{[1
]}

Leigh, David A. ^{[1
]}

Lusby, Paul J. ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 26期

关键词：

coordination modes; macrocycles; palladium; polyrotaxanes; rotaxanes; template synthesis;

D O I：

10.1002/anie.200700933

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One for all: The iteration of three simple steps - complexation, macrocyclization, and demetalation - enables the synthesis of multi-ring rotaxanes with only one template site (see picture). This efficient and effective strategy enables both the number and the order in which macrocycles are assembled onto a thread to be controlled with unprecedented precision. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5015 / 5019

页数：5

共 76 条

[1]

Amabilino D. B., 1994, ANGEW CHEM, V106, P450

[2] Oligocatenanes made to order [J].

Amabilino, DB ;

Ashton, PR ;

Balzani, V ;

Boyd, SE ;

Credi, A ;

Lee, JY ;

Menzer, S ;

Stoddart, JF ;

Venturi, M ;

Williams, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (18) :4295-4307

[3] Aggregation of self-assembling branched [n]rotaxanes [J].

Amabilino, DB ;

Asakawa, M ;

Ashton, PR ;

Ballardini, R ;

Balzani, V ;

Belohradsky, M ;

Credi, A ;

Higuchi, M ;

Raymo, FM ;

Shimizu, T ;

Stoddart, JF ;

Venturi, M ;

Yase, K .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (09) :959-972

[4] Interlocked and intertwined structures and superstructures [J].

Amabilino, DB ;

Stoddart, JF .

CHEMICAL REVIEWS, 1995, 95 (08) :2725-2828

[5] THE SELF-ASSEMBLY OF BRANCHED [N]ROTAXANES-THE FIRST STEP TOWARDS DENDRITIC ROTAXANES [J].

AMABILINO, DB ;

ASHTON, PR ;

BELOHRADSKY, M ;

RAYMO, FM ;

STODDART, JF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (07) :751-753

[6] The five-stage self-assembly of a branched heptacatenane [J].

Amabilino, DB ;

Ashton, PR ;

Boyd, SE ;

Lee, JY ;

Menzer, S ;

Stoddart, JF ;

Williams, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19) :2070-2072

[7] Self-assembly of [n]rotaxanes bearing dendritic stoppers [J].

Amabilino, DB ;

Ashton, PR ;

Balzani, V ;

Brown, CL ;

Credi, A ;

Frechet, JMJ ;

Leon, JW ;

Raymo, FM ;

Spencer, N ;

Stoddart, JF ;

Venturi, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (48) :12012-12020

[8] THE 2-STEP SELF-ASSEMBLY OF [4]-CATENANE AND [5]CATENANE [J].

AMABILINO, DB ;

ASHTON, PR ;

REDER, AS ;

SPENCER, N ;

STODDART, JF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (04) :433-437

[9] MOLECULAR MECCANO .2. SELF-ASSEMBLY OF [ETA]CATENANES [J].

AMABILINO, DB ;

ASHTON, PR ;

BROWN, CL ;

CORDOVA, E ;

GODINEZ, LA ;

GOODNOW, TT ;

KAIFER, AE ;

NEWTON, SP ;

PIETRASZKIEWICZ, M ;

PHILP, D ;

RAYMO, FM ;

REDER, AS ;

RUTLAND, MT ;

SLAWIN, AMZ ;

SPENCER, N ;

STODDART, JF ;

WILLIAMS, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (04) :1271-1293

[10]

AMABILINO DB, 1997, ANGEW CHEM, V109, P2070

← 1 2 3 4 5 6 7 8 →