One template, multiple rings: Controlled iterative addition of macrocycles onto a single binding site rotaxane thread

被引：72

作者：

Fuller, Anne-Marie L. ^{[1
]}

Leigh, David A. ^{[1
]}

Lusby, Paul J. ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 26期

关键词：

coordination modes; macrocycles; palladium; polyrotaxanes; rotaxanes; template synthesis;

D O I：

10.1002/anie.200700933

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One for all: The iteration of three simple steps - complexation, macrocyclization, and demetalation - enables the synthesis of multi-ring rotaxanes with only one template site (see picture). This efficient and effective strategy enables both the number and the order in which macrocycles are assembled onto a thread to be controlled with unprecedented precision. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5015 / 5019

页数：5

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