4-connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions:: Kagome lattice and the M6L12 octahedron

被引:167
作者
Liu, YL
Kravtsov, VC
Beauchamp, DA
Eubank, JF
Eddaoudi, M
机构
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[2] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
关键词
D O I
10.1021/ja051259q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3·2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron. Copyright © 2005 American Chemical Society.
引用
收藏
页码:7266 / 7267
页数:2
相关论文
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