An easy preparation of a silica gel supported chromium trioxide oxidant and its use in the selective oxidation of alcohols

被引：28

作者：

Khadilkar, B

Chitnavis, A

Khare, A

机构：

[1] Chemistry Division, Department of Chemical Technology, University of Bombay, Matunga

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 02期

关键词：

D O I：

10.1080/00397919608003605

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A silica gel supported chromium trioxide reagent was prepared by co-grinding anhydrous CrO3 with silica gel in appropriate proportion. The reagent was used in equimolar quantity to oxidise alcohols to carbonyl compounds with good yields and complete selectivity. The reagent has a good shelf life of at least two months.

引用

页码：205 / 210

页数：6

共 24 条

[1]

Anderson H., 1973, SYNTHETIC COMMUN, V3, P115

[2]

[Anonymous], [No title captured]

[3] OXIDATION OF SECONDARY ALCOHOLS IN DIETHYL ETHER WITH AQUEOUS CHROMIC ACID - CONVENIENT PROCEDURE FOR PREPARATION OF KETONES IN HIGH EPIMERIC PURITY [J].