Synthesis and characterization of the gold(I) tris(ethylene) complex [AU(C2H4)3][SbF6]

被引：78

作者：

Dias, H. V. Rasika ^{[1
]}

Fianchini, Mauro ^{[1
]}

Cundari, Thomas R. ^{[2
]}

Campana, Charles F. ^{[3
]}

机构：

[1] Univ Texas Arlington, Dept Chem & Biochem, Arlington, TX 76019 USA

[2] Univ N Texas, Dept Chem, CASCaM, Denton, TX 76203 USA

[3] Bruker AXS Inc, Single Crystal Diffract, Madison, WI 53711 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 03期

关键词：

alkene ligands; density functional calculations; gold; pi interactions; X-ray diffraction;

D O I：

10.1002/anie.200703515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ethylene el dorado: Gold(I) unusually takes up three ethylene molecules in a spoked-wheel arrangement (see picture). The complex was synthesized as the hexafluoroantimonate salt and structurally characterized. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：556 / 559

页数：4

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