Fast charging LiFePO4

被引：61

作者：

Yamada, A ^{[1
]}

Yonemura, M ^{[1
]}

Takei, Y ^{[1
]}

Sonoyama, N ^{[1
]}

Kanno, R ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Interdisciprinary Grad Sch Sci & Engn, Yokohama, Kanagawa 2268502, Japan

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2005年 / 8卷 / 01期

关键词：

D O I：

10.1149/1.1836117

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

An excellent fast charging ability for olivine LiFePO4 is demonstrated with respect to its advantageous open-circuit voltage of 3.4 V vs. Li/Li+ with an appropriately large overvoltage margin to the electrolyte oxidation, structural integrity under the nonequilibrium state induced by the large overpotential, and moderate electrochemical activity easily enhanced to the practical level by efficient nanocomposite formation. The current relaxation to the applied stepwise voltage of 4.2 V vs. Li/ Li+ for the LixFePO(4) was fast enough to consume most of the theoretical capacity within 10-20 min and the speed is competitive with that of the conventional electrode composite of LixMn2O4, while the capacity consumption of LixMnPO4 under the identical experimental conditions was almost null. (C) 2004 The Electrochemical Society.

引用

页码：A55 / A58

页数：4

共 23 条

[1] Aromatic compounds as redox shuttle additives for 4 V class secondary lithium batteries [J].