Synthesis and properties of isoxazolo[60]fullerene -: Donor dyads

被引：65

作者：

Langa, F ^{[1
]}

de la Cruz, P

Espíldora, E

González-Cortés, A

de la Hoz, A

López-Arza, V

机构：

[1] Univ Castilla La Mancha, Fac Ciencias Quim, Toledo 45071, Spain

[2] Univ Castilla La Mancha, Fac Ciencias Medio Ambiente, Toledo 45071, Spain

[3] Univ Castilla La Mancha, Escuela Ingn Tecn Ind, Toledo 45071, Spain

[4] Univ Complutense, Fac Quim, E-28040 Madrid, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 65卷 / 25期

关键词：

D O I：

10.1021/jo0010532

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of isoxazolo[60]fullerenes has been prepared in one pot from aldoximes under microwave irradiation. Several donors and accepters were used as Substituents. The absorption and emission spectra of these compounds in polar solvents suggest a weak charge-transfer interaction between the oxygen atom of the isoxazoline moiety and the C-60 cage, as well as a stronger interaction between the donor and the fullerene cage when the attached groups are p-N,N-dimethylaniline or ferrocene. The electrochemical properties of the compounds were investigated and they Show the same or better acceptor character than C-60 in all cases. Theoretical calculations support the results obtained; Solvent effects in the H-1 NMR spectra have been determined and provide useful information concerning the polarization of dyads.

引用

页码：8675 / 8684

页数：10

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