Synthesis, structure and spectroscopic characterization of water-soluble CdS nanoparticles

被引:47
作者
Barglik-Chory, C [1 ]
Buchold, D
Schmitt, M
Kiefer, W
Heske, C
Kumpf, C
Fuchs, O
Weinhardt, L
Stahl, A
Umbach, E
Lentze, M
Geurts, J
Müller, G
机构
[1] Univ Wurzburg, D-97070 Wurzburg, Germany
[2] Univ Wurzburg, Lehrstuhl 2, Inst Chem Phys, D-97070 Wurzburg, Germany
关键词
D O I
10.1016/j.cplett.2003.08.068
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present a facile approach for synthesizing bio-stabilized CdS nanoparticles in gram quantities. The particles were characterized by optical spectroscopy, Raman spectroscopy, soft X-ray emission spectroscopy, XRD, thermal and chemical analysis. The size of the particles is about 2.3 nm, with a CdS core of 1.3 nm diameter and an organic shell of 0.5 nm thickness which is thermally stable up to 200 degreesC. The chemical composition, surface termination, and optical proper-ties are analysed. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:443 / 451
页数:9
相关论文
共 35 条
[1]   Perspectives on the physical chemistry of semiconductor nanocrystals [J].
Alivisatos, AP .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13226-13239
[2]   Properties of glutathione- and phytochelatin-capped CdS bionanocrystallites [J].
Bae, W ;
Mehra, RK .
JOURNAL OF INORGANIC BIOCHEMISTRY, 1998, 69 (1-2) :33-43
[3]   Characteristics of glutathione-capped ZnS nanocrystallites [J].
Bae, WO ;
Abdullah, R ;
Henderson, D ;
Mehra, RK .
BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1997, 237 (01) :16-23
[4]   Influence of synthesis parameters on the growth of US nanoparticles in colloidal solution and determination of growth kinetics using Karhunen-Loeve decomposition [J].
Barglik-Chory, C ;
Münster, AF ;
Strohm, H ;
Remenyi, C ;
Müller, G .
CHEMICAL PHYSICS LETTERS, 2003, 374 (3-4) :319-325
[5]  
Brown M.E., 1988, Introduction to Thermal Analysis
[6]   QUANTUM CRYSTALLITES AND NONLINEAR OPTICS [J].
BRUS, L .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1991, 53 (06) :465-474
[7]   Chemical approaches to semiconductor nanocrystals [J].
Brus, L .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1998, 59 (04) :459-465
[8]  
Gaponik N, 2002, ADV MATER, V14, P879, DOI 10.1002/1521-4095(20020618)14:12<879::AID-ADMA879>3.0.CO
[9]  
2-A