Atomization of vanadium in a graphite furnace: Experimental and theoretical modelling of surface interactions

被引：13

作者：

Benzo, Z ^{[1
]}

Montero, T ^{[1
]}

Quintal, M ^{[1
]}

Sierraalta, A ^{[1
]}

Ruette, F ^{[1
]}

机构：

[1] INST VENEZOLANO INVEST CIENT, CTR QUIM, LAB QUIM COMPUTAC, CARACAS 1020A, VENEZUELA

来源：

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY | 1996年 / 11卷 / 06期

关键词：

vanadium; electrothermal atomic absorption spectrometry; theoretical modelling; acid interference;

D O I：

10.1039/ja9961100445

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Experimental and theoretical modelling of the atomization of V on a graphite surface has been carried out in order to study the activity inherent to the surface. The most important variables and interactions on atomization of V have been investigated using factorial designs and response surface methodology. The effect of mineral acids on the memory effects usually encountered during the electrothermal atomization of V in graphite atomizers has been evaluated by modelling the coadsorption of protons on the graphite surface.

引用

页码：445 / 452

页数：8

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