Preparation and properties of organic radical compounds directed toward spin systems with multi-property

被引:9
作者
Nakatsuji, S [1 ]
机构
[1] Himeji Inst Technol, Grad Sch Sci, Ako, Hyogo 6781297, Japan
关键词
organic radicals; aminoxyl radicals; TEMPO radicals; nitronyl nitroxide radicals; magnetic property; magnetic interactions; liquid crystalline property; photo-functionality; conducting property; pressure-responsive property;
D O I
10.5059/yukigoseikyokaishi.61.670
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Preparation and properties of organic radicals directed toward spin systems with multi-property are described, in which aminoxyl (nitroxide) radicals are incorporated as the crucial building blocks. Those include such organic radicals that exhibit the magnetic properties responding to or correlating with outer stimuli as heat (liquid crystalline property), light (photo-functionality), electron/hole (conducting property), or pressure (pressure-responsive property).
引用
收藏
页码:670 / 681
页数:12
相关论文
共 81 条
[41]   A soft-hard-tunable molecule-based magnet via photo-induced spin-flopping transition in a MnTEtOPP-TCNE charge transfer salt [J].
Nagai, K ;
Iyoda, T ;
Fujishima, A ;
Hashimoto, K .
SOLID STATE COMMUNICATIONS, 1997, 102 (11) :809-812
[42]   Synthesis and applications of optically active nitroxides [J].
Naik, N ;
Braslau, R .
TETRAHEDRON, 1998, 54 (5-6) :667-696
[43]  
Nakatani K, 2001, ADV MATER, V13, P1411, DOI 10.1002/1521-4095(200109)13:18<1411::AID-ADMA1411>3.0.CO
[44]  
2-Y
[45]   2-(2′-Halophenyl)-α-nitronyl nitroxides [J].
Nakatsuji, S ;
Saiga, M ;
Haga, N ;
Naito, A ;
Hirayama, T ;
Nakagawa, M ;
Oda, Y ;
Anzai, H ;
Suzuki, K ;
Enoki, T ;
Mito, M ;
Takeda, K .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (03) :275-280
[46]  
Nakatsuji S, 1998, Z NATURFORSCH B, V53, P495
[47]   Novel CT complexes derived from 4-alkylamino-TEMPO and 2,4,6,8-Tetracyanoazulene [J].
Nakatsuji, S ;
Mizumoto, M ;
Takai, A ;
Akutsu, H ;
Yamada, J ;
Kawamura, H ;
Schmitt, S ;
Hafner, K .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 348 :1-6
[48]   Preparation and properties of 4-amino-TEMPO-substituted benzoquinone derivatives and related charge-transfer complexes [J].
Nakatsuji, S ;
Akashi, N ;
Suzuki, K ;
Enoki, T ;
Anzai, H .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (11) :2555-2559
[49]   Deoxygenation reaction of phenyl nitronyl nitroxides with the strong acceptors TCNQF4 and TCNQ [J].
Nakatsuji, S ;
Takai, A ;
Ojima, T ;
Anzai, H .
JOURNAL OF CHEMICAL RESEARCH, 1999, (10) :620-621
[50]  
Nakatsuji S, 2002, RECENT RESEARCH DEVELOPMENTS IN ORGANIC & BIOORGANIC CHEMISTRY, VOL 5, P1