Metal-organic scandium framework:: Useful material for hydrogen storage and catalysis

被引：140

作者：

Perles, J ^{[1
]}

Iglesias, M ^{[1
]}

Martín-Luengo, MA ^{[1
]}

Monge, MA ^{[1
]}

Ruiz-Valero, C ^{[1
]}

Snejko, N ^{[1
]}

机构：

[1] CSIC, Inst Ciencia Mat, E-28049 Madrid, Spain

来源：

CHEMISTRY OF MATERIALS | 2005年 / 17卷 / 23期

关键词：

D O I：

10.1021/cm051362e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The 3D polymeric terephthalate of scandium has been synthesized and its structure solved by single-crystal XRD. It was obtained as a single phase and characterized and tested as a hydrogen and nitrogen adsorbent and heterogeneous catalyst as a redox agent in the oxidation of sulfides. The compound shows a BET area of 721 m(2) g(-1) with a high C-BET = 7000. The high chemical and thermal stability and excellent hydrogen sorption properties make this compound a useful material for hydrogen storage.

引用

页码：5837 / 5842

页数：6

共 38 条

[1] VIII(OH){O2C-C6H4-CO2}•(HO2C-C6H4-CO2H)x(DMF)y(H2O)z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology:: reticular synthesis with infinite inorganic building blocks? [J].