Chemistry and application of flexible porous coordination polymers

被引:185
作者
Bureekaew, Sareeya [1 ]
Shimomura, Satoru [1 ]
Kitagawa, Susumu [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
关键词
porous coordination polymer; storage; separation; flexible framework; porosity;
D O I
10.1088/1468-6996/9/1/014108
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Porous coordination polymers (PCPs), which are microporous materials, have been given much attention from both scientific and commercial aspects regarding their application to gas storage, gas separation and catalytic reaction because of the regularity of their pore shape and pore size, accompanied with the functionality. Moreover, in recent years, flexible PCPs, which are structurally transformable depending upon external stimuli, have been attractive because they provide unique properties, dissimilar to those of zeolites. In this review, the chemistry and application of flexible crystalline PCPs are summarized and discussed.
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页数:12
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