Series of Isostructural Planar Lanthanide Complexes [Ln4III(μ3-OH)2(mdeaH)2(piv)8] with Single Molecule Magnet Behavior for the Dy4 Analogue

被引：221

作者：

Abbas, Ghulam ^{[1
]}

Lan, Yanhua ^{[1
]}

Kostakis, George E. ^{[2
]}

Wernsdorfer, Wolfgang ^{[3
,4
]}

Anson, Christopher E. ^{[1
]}

Powell, Annie K. ^{[1
,2
]}

机构：

[1] Karlsruhe Inst Technol, Inst Inorgan Chem, D-76131 Karlsruhe, Germany

[2] Karlsruhe Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[3] CNRS, Inst Neel, F-38042 Grenoble 9, France

[4] Univ Grenoble 1, F-38042 Grenoble 9, France

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 17期

关键词：

STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMERS; ANISOTROPIC BARRIER; HYDROXO COMPLEXES; BUILDING-BLOCK; ION LN; CLUSTERS; CHEMISTRY; MAGNETIZATION; NITROPHENOLATE;

D O I：

10.1021/ic1011605

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of five isostructural tetranuclear lanthanide complexes of formula [Ln(4)(mu(3)-OH)(2)(mdeaH)(2)(piv)(8)], (mdeaH(2) = N-methyldiethanolamine; piv = pivalate; Ln = Tb (1), Dy (2), Ho (3), Er (4), and Tm (5)) have been synthesized and characterized. These clusters have a planar "butterfly" Ln(4) core. Magnetically, the Ln(III) ions are weakly coupled in all cases; the Dy-4 compound 2 shows Single Molecule Magnet (SMM) behavior.

引用

页码：8067 / 8072

页数：6

共 66 条

[51] Dinuclear lanthanide(III) complexes from the use of di-2-pyridyl ketone: Preparation, structural characterization and spectroscopic studies
Thiakou, Katerina A.
Bekiari, Vlasoula
Raptopoulou, Catherine P.
Psycharis, Vassilis
Lianos, Panagiotis
Perlepes, Spyros P.
[J]. POLYHEDRON, 2006, 25 (15) : 2869 - 2879
[52] Direct hydrolytic route to molecular oxo-hydroxo lanthanide clusters
Wang, RY
Carducci, MD
Zheng, ZP
[J]. INORGANIC CHEMISTRY, 2000, 39 (09) : 1836 - 1837
[53] Halide-templated assembly of polynuclear lanthanide-hydroxo complexes
Wang, RY
Selby, HD
Liu, H
Carducci, MD
Jin, TZ
Zheng, ZP
Anthis, JW
Staples, RJ
[J]. INORGANIC CHEMISTRY, 2002, 41 (02) : 278 - 286
[54] Toward constructing nanoscale hydroxo-lanthanide clusters: syntheses and characterizations of novel tetradecanuclear hydroxo-lanthanide clusters
Wang, RY
Song, DT
Wang, SM
[J]. CHEMICAL COMMUNICATIONS, 2002, (04) : 368 - 369
[55] Wang RY, 1999, ANGEW CHEM INT EDIT, V38, P1813, DOI 10.1002/(SICI)1521-3773(19990614)38:12<1813::AID-ANIE1813>3.0.CO
[56] 2-3
[57] Classical and quantum magnetization reversal studied in nanometer-sized particles and clusters
Wernsdorfer, W
[J]. ADVANCES IN CHEMICAL PHYSICS, VOL 118, 2001, 118 : 99 - 190
[58] Self assembly, structure and properties of the decanuclear lanthanide ring complex, Dy10(OC2H4OCH3)30
Westin, LG
Kritikos, M
Caneschi, A
[J]. CHEMICAL COMMUNICATIONS, 2003, (08) : 1012 - 1013
[59] Synthesis and structural characterization of nonanuclear lanthanide complexes
Xu, G
Wang, ZM
He, Z
Lu, Z
Liao, CS
Yan, CH
[J]. INORGANIC CHEMISTRY, 2002, 41 (25) : 6802 - 6807
[60] Praseodymium(III)-based bis-metallacalix[4]arene with host-guest behaviour
Xu, Gong-Feng
Gamez, Patrick
Teat, Simon J.
Tang, Jinkui
[J]. DALTON TRANSACTIONS, 2010, 39 (18) : 4353 - 4357

← 1 2 3 4 5 6 7 →