Water-in-oil microemulsion preparation and characterization of Cs2[Mo6X14]@SiO2 phosphor nanoparticles based on transition metal clusters (X = Cl, Br, and I)

被引：101

作者：

Grasset, Fabien ^{[1
,2
]}

Dorson, Frederic

Cordier, Stephane ^{[1
]}

Molard, Yann ^{[1
]}

Perrin, Christiane ^{[1
]}

Marie, Anne-Marie ^{[3
]}

Sasaki, Toshio ^{[2
]}

Haneda, Hajime ^{[2
]}

Bando, Yoshio ^{[2
]}

Mortier, Michel ^{[4
]}

机构：

[1] Univ Rennes 1, UR1 CNRS 6226, UMR Sci Chim Rennes, Grp Chim Solide & Mat, F-35042 Rennes, France

[2] Natl Inst Mat Sci, Int Ctr Young Scientists, Tsukuba, Ibaraki 3050044, Japan

[3] Inst Mat Jean Rouxel IMN, UMR 6502, F-44322 Nantes 03, France

[4] Ecole Natl Super Chim Paris, CNRS, UMR 7574, F-75005 Paris, France

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 01期

关键词：

D O I：

10.1002/adma.200701686

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monodisperse Cs2Mo6X14@SiO2 (X = Cl, Br, I) luminescent nanoparticles are synthesized by a water-in-oil microemulsion technique. They emit in the red and near-infrared window (600-900 nm), a region of interest for bio-imaging technologies. Microscopy studies (SEM, TEM and HAADF-STEM, see figure) show a good dispersion of the [Mo6X14](2-) anions within the @SiO2 nanoparticles and that the nanoparticles are homogeneous with a regular spherical shape of 45 nm diameter.

引用

页码：143 / +

页数：7

共 34 条

[1] Controlled hydrolysis of tetraethoxysilane in a nonionic water-in-oil microemulsion: a statistical model of silica nucleation [J].