Laser-induced crystal growth and morphology control of benzopinacol produced from benzophenone in ethanol/water mixed solution

被引:53
作者
Okutsu, T [1 ]
Nakamura, K [1 ]
Haneda, H [1 ]
Hiratsuka, H [1 ]
机构
[1] Gunma Univ, Dept Chem, Kiryu, Gumma 3768515, Japan
关键词
D O I
10.1021/cg0340493
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Laser-induced precipitation and crystal growth were observed by an irradiation of benzophenone in an ethanol and water mixed solvent. The crystal was composed of benzopinacol produced from excited benzophenone through a benzophenone ketyl radical. Polyhedral, skeletal, and dendrite morphologies of benzopinacol were controlled by laser energy. This is the first example of a photochemical morphology control of a crystal.
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收藏
页码:113 / 115
页数:3
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