Enantioselective copper catalyzed Diels-Alder reaction using chiral quinoline-phosphine ligand

被引：40

作者：

Brunel, JM ^{[1
]}

Del Campo, B ^{[1
]}

Buono, G ^{[1
]}

机构：

[1] Fac Sci & Tech St Jerome, ENSSPICAM, CNRS, F-13397 Marseille 20, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(98)02210-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new chiral copper (II) catalyst was prepared from Cu(OTf)(2) and chiral pyridine-phosphine ligands 1-2 in dichloromethane and used in the Diels-Alder reaction of 3-acryloyl-1,3-oxazolidine-2-one with cyclopentadiene leading to enantioselectivities up to 99%. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：9663 / 9666

页数：4

共 23 条

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