Enantioselective palladium catalyzed allylic substitution with new chiral pyridine-phosphine ligands

被引：52

作者：

Brunel, JM ^{[1
]}

Constantieux, T ^{[1
]}

Labande, A ^{[1
]}

Lubatti, F ^{[1
]}

Buono, G ^{[1
]}

机构：

[1] FAC SCI & TECH ST JEROME,UMR 6516 CNRS,ECOLE NATL SUPER SYNTH PROCEDES & INGENIERIE CHIM,F-13397 MARSEILLE 20,FRANCE

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(97)01346-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of new chiral pyridine-phosphine ligands 1-3 was achieved and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenyl-2-propenyl acetate 4 with dimethylmalonate 5. Enantioselectivities up to 87% were obtained. (C) 1997 Elsevier Science Ltd.

引用

页码：5971 / 5974

页数：4

共 19 条

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