Synthesis of homochiral pyridyl, bipyridyl and phosphino derivatives of 2,2-dimethyl-1,3-dioxolane: Use in asymmetric catalysis

被引:43
作者
Chelucci, G
Cabras, MA
Botteghi, C
Basoli, C
Marchetti, M
机构
[1] UNIV VENICE,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY
[2] CNR,IST APPLICAZ TECN CHIM AVANZATE PROBLEMI AGRO,I-07100 SASSARI,ITALY
关键词
D O I
10.1016/0957-4166(96)00086-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Homochiral pyridyl, bipyridyl and phosphino derivatives of 2,2-dimethyl-1,3-dioxolane were prepared from L-(+)-tartrate. These compounds were assessed in metal catalyzed asymmetric addition of diethylzinc to benzaldehyde, hydroformylation of styrene, hydrocarboethoxylation of styrene and allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. (C) 1996 Elsevier Science Ltd
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页码:885 / 895
页数:11
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