PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION-REACTIONS OF PROCHIRAL AND RACEMIC ALLYL ACETATES

被引:57
作者
DAWSON, GJ
WILLIAMS, JMJ
COOTE, SJ
机构
[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND
[2] GLAXO RES & DEV LTD,WARE SG12 0DP,HERTS,ENGLAND
关键词
D O I
10.1016/0040-4039(94)02286-K
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The palladium catalysed reaction between nan-symmetrical allyl acetates and sodiodimethylmalonate proceeds in high yields and enantioselectivities (up to 99% ee) using a diphenylphosphinoaryl oxazoline ligand.
引用
收藏
页码:461 / 462
页数:2
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