Microwave synthesis and electrochemical properties of LiCo1-xMxO2 (M = Al and Mg) cathodes for Li-ion rechargeable batteries

被引：34

作者：

Elumalai, P

Vasan, HN ^{[1
]}

Munichandraiah, N

机构：

[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

[2] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

JOURNAL OF POWER SOURCES | 2004年 / 125卷 / 01期

关键词：

Li-ion battery; cathodes; aluminum and magnesium substitution; microwave synthesis; discharge capacity;

D O I：

10.1016/S0378-7753(03)00815-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single phase LiCo1-xMxO2 (M = Al and Mg) cathode materials for Li-ion batteries are synthesized by microwave dielectric heating with a reaction time less than 20 min. Aluminium forms solid solutions up to a composition of x = 0.5 and magnesium up to x = 0.2. Lattice constants are found to vary with the composition. The compounds are electrochemically active with good discharge capacity. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：77 / 84

页数：8

共 39 条

[1]

AHMED I, 1991, J MICROWAVE POWER EE, V26, P128

[2] X-ray diffraction, EPR, and 6Li and 27Al MAS NMR study of LiAlO2-LiCoO2 solid solutions [J].