Synthesis of carbon nanohorns by a gas-injected arc-in-water method and application to catalyst-support for polymer electrolyte fuel cell electrodes

被引:25
作者
Sano, Noriaki [1 ]
Kimura, Yuu [1 ]
Suzuki, Tatsuhiro [1 ]
机构
[1] Univ Hyogo, Dept Mech & Syst Engn, Himeji, Hyogo 6712201, Japan
关键词
D O I
10.1039/b717302d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Single-wall carbon nanohorns (SWNHs) were synthesized by a gas-injected arc-in-water method with varied gas flow rate, arc current, and gas component to investigate their influence on the purity, the yield, and the structure of the products, in which the quenching rate of the carbon vapour in the optimized condition for SWNHs formation was revealed as order of mega-K s(-1), and thereafter the characteristics of the as-grown SWNHs for the use of a fuel cell electrode were related with the arc current in their production.
引用
收藏
页码:1555 / 1560
页数:6
相关论文
共 20 条
[1]   Synthesis of multiwall carbon nanotubes by electric arc discharge in liquid environments [J].
Antisari, MV ;
Marazzi, R ;
Krsmanovic, R .
CARBON, 2003, 41 (12) :2393-2401
[2]   Oxidation and porosity evaluation of budlike single-wall carbon nanohorn aggregates [J].
Bekyarova, E ;
Kaneko, K ;
Kasuya, D ;
Murata, K ;
Yudasaka, M ;
Iijima, S .
LANGMUIR, 2002, 18 (10) :4138-4141
[3]   Continuous carbon nanotube production in underwater AC electric arc [J].
Biró, LP ;
Horváth, ZE ;
Szalmás, L ;
Kertész, K ;
Wéber, F ;
Juhász, G ;
Radnóczi, G ;
Gyulai, J .
CHEMICAL PHYSICS LETTERS, 2003, 372 (3-4) :399-402
[4]   Growth process conditions of vertically aligned carbon nanotubes using plasma enhanced chemical vapor deposition [J].
Chhowalla, M ;
Teo, KBK ;
Ducati, C ;
Rupesinghe, NL ;
Amaratunga, GAJ ;
Ferrari, AC ;
Roy, D ;
Robertson, J ;
Milne, WI .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) :5308-5317
[5]   LARGE-SCALE SYNTHESIS OF CARBON NANOTUBES [J].
EBBESEN, TW ;
AJAYAN, PM .
NATURE, 1992, 358 (6383) :220-222
[6]   Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes [J].
Hata, K ;
Futaba, DN ;
Mizuno, K ;
Namai, T ;
Yumura, M ;
Iijima, S .
SCIENCE, 2004, 306 (5700) :1362-1364
[7]  
Hsin YL, 2001, ADV MATER, V13, P830, DOI 10.1002/1521-4095(200106)13:11<830::AID-ADMA830>3.0.CO
[8]  
2-4
[9]   Nano-aggregates of single-walled graphitic carbon nano-horns [J].
Iijima, S ;
Yudasaka, M ;
Yamada, R ;
Bandow, S ;
Suenaga, K ;
Kokai, F ;
Takahashi, K .
CHEMICAL PHYSICS LETTERS, 1999, 309 (3-4) :165-170
[10]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58