Crystal engineering: Toward intersecting channels from a neutral network with a bcu-type topology

被引：204

作者：

Luo, TT

Tsai, HL

Yang, SL

Liu, YH

Yaday, RD

Su, CC

Ueng, CH

Lin, LG

Lu, KL ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Taiwan Normal Univ, Dept Chem, Taipei 116, Taiwan

[3] Natl Cheng Kung Univ, Dept Chem, Tainan 701, Taiwan

[4] Chinese Culture Univ, Dept Chem, Taipei 111, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 37期

关键词：

crystal engineering; microporous materials; organic-inorganic hybrid composites; self-assembly; topochemistry;

D O I：

10.1002/anie.200462674

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) In rare form: Although the structure of the body-centered cubic (bcu) net is commonly found in textbooks, its eight-connected topology is extremely rare in metal-organic frameworks owing to severe geometric requirements. The first example of a highly porous, neutral bcu-type framework (see picture) assembled from a unique eight-connected tricopper cluster and a 5-(4-pyridyl)tetrazolate ligand as linker is reported. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6063 / 6067

页数：5

共 83 条

[81] Hydrothermal preparation of novel Cd(II) coordination polymers employing 5-(4-pyridyl)tetrazolate as a bridging ligand [J].