Aerobic oxidation of isopropanol catalysed by peroxovanadium complexes: mechanistic insights

被引：24

作者：

Bonchio, M

Bortolini, O

Conte, V

Primon, S

机构：

[1] Univ Foggia, Fac Agr, IPPA, I-71100 Foggia, Italy

[2] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy

[3] CNR CMRO, Dipartimento Chim Organ, I-35131 Padua, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2001年 / 05期

关键词：

D O I：

10.1039/b009958i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aerobic oxidation of (PrOH)-O-i to acetone with parallel reduction of dioxygen to hydrogen peroxide is observed for acid (PrOH)-O-i-H2O solutions of peroxovanadates. Spectroscopic evidence, obtained with a combined use of V-51-NMR, UV-VIS and ESI-MS techniques, is presented for a monoperoxovanadium-catalysed inner-sphere oxidation of the alcohol coordinated to the metal center.

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页码：763 / 765

页数：3

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