Aerobic oxidation of isopropanol catalysed by peroxovanadium complexes: mechanistic insights

被引：24

作者：

Bonchio, M

Bortolini, O

Conte, V

Primon, S

机构：

[1] Univ Foggia, Fac Agr, IPPA, I-71100 Foggia, Italy

[2] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy

[3] CNR CMRO, Dipartimento Chim Organ, I-35131 Padua, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2001年 / 05期

关键词：

D O I：

10.1039/b009958i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aerobic oxidation of (PrOH)-O-i to acetone with parallel reduction of dioxygen to hydrogen peroxide is observed for acid (PrOH)-O-i-H2O solutions of peroxovanadates. Spectroscopic evidence, obtained with a combined use of V-51-NMR, UV-VIS and ESI-MS techniques, is presented for a monoperoxovanadium-catalysed inner-sphere oxidation of the alcohol coordinated to the metal center.

引用

收藏

页码：763 / 765

页数：3

相关论文

共 23 条

[11] V-51-NMR INVESTIGATION ON THE FORMATION OF PEROXO VANADIUM COMPLEXES IN AQUEOUS-SOLUTION - SOME NOVEL OBSERVATIONS [J].

CONTE, V ;

DIFURIA, F ;

MORO, S .

JOURNAL OF MOLECULAR CATALYSIS, 1994, 94 (03) :323-333

[12] Studies directed toward the prediction of the oxidative reactivity of vanadium peroxo complexes in water, Correlations between the nature of the ligands and V-51-NMR chemical shifts [J].

Conte, V ;

DiFuria, F ;

Moro, S .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 104 (02) :159-169

[13] Solvation, preferential solvation and complexation by the solvent of peroxovanadium complexes studied by 51V NMR spectroscopy.: Correlations with the oxidative reactivity [J].

Conte, V ;

Di Furia, F ;

Moro, S .

INORGANICA CHIMICA ACTA, 1998, 272 (1-2) :62-67

[14] ONE-ELECTRON OXIDATION OF 2-PROPANOL BY VANADIUM AND MOLYBDENUM PEROXO COMPLEXES [J].

CONTE, V ;

DIFURIA, F ;

MODENA, G .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (08) :1665-1669

[15] SYNTHESIS AND STRUCTURE OF THE NEW ORGANOMETALLIC POLYOXOVANADATES, ([(ETA-C8H12)IR]2(V4O12))2- AND [(ETA-C8H12)IR(V4O12)]3- [J].

DAY, VW ;

KLEMPERER, WG ;

YAGASAKI, A .

CHEMISTRY LETTERS, 1990, (08) :1267-1270

[16] Vanadium in modern organic synthesis [J].

Hirao, T .

CHEMICAL REVIEWS, 1997, 97 (08) :2707-2724

[17] FORMATION AND DECOMPOSITION OF PEROXOVANADIUM(V) COMPLEXES IN AQUEOUS-SOLUTION [J].

JASWAL, JS ;

TRACEY, AS .

INORGANIC CHEMISTRY, 1991, 30 (19) :3718-3722

[18] O-17 NMR AS A TOOL FOR STUDYING OXYGENATED TRANSITION-METAL DERIVATIVES - 1ST DIRECT O-17 NMR OBSERVATIONS OF TRANSITION-METAL-BONDED PEROXIDIC OXYGEN-ATOMS - EVIDENCE FOR THE ABSENCE OF OXO-PEROXO OXYGEN-EXCHANGE IN MOLYBDENUM(VI) COMPOUNDS [J].

POSTEL, M ;

BREVARD, C ;

ARZOUMANIAN, H ;

RIESS, JG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (15) :4922-4926

[19]

REHDER D, 1990, VANADIUM BIOL SYSTEM, pCH10

[20]

Thiel WR, 1999, ANGEW CHEM INT EDIT, V38, P3157, DOI 10.1002/(SICI)1521-3773(19991102)38:21<3157::AID-ANIE3157>3.0.CO