Artificial metalloenzymes as selective catalysts in aqueous media

被引：153

作者：

Steinreiber, Johannes ^{[1
]}

Ward, Thomas R. ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Chem, CH-2009 Neuchatel, Switzerland

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 5-7期

关键词：

asymmetric catalysis; artificial metalloenzymes; hybrid catalysts; designed evolution; redox reactions; hydrolysis; C-C bond formation; DNA-cleavage;

D O I：

10.1016/j.ccr.2007.09.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fusion of homogeneous and enzymatic catalysis has recently drawn attention due to reported novel activities and high selectivities. The incorporation of metal-catalysts into proteins combines the advantages of both catalytic strategies. Herein we summarize recent approaches of artificial metalloenzymes applied to catalysis. The discussion includes different strategies of anchoring and screening for improved selectivity. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：751 / 766

页数：16

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