Polyaniline-carbon composite films as supports of Pt and PtRu particles for methanol electrooxidation

Vulcan XC-72 carbon black particles (average size: ca. 50 nm) was incorporated into polyaniline (PANI) matrix by an electrochemical codeposition technique during the electropolymerization process. The doping by carbon particles leads to a higher polymeric degree and a lower defect density in the PANI structure. Furthermore, the incorporation of carbon particles not only increases the electrochemical accessible surface areas (S-a) and electron conductivity of the PANI film, but also decreases charge transfer resistance at PANI/electrolyte interfaces. Therefore, as expected, a fabricated PANI + C composite film with dispersed Pt and PtRu particles exhibited excellent electrocatalytic activity for methanol oxidation due to better Pt dispersion and utilization. The PANI + C composite film is more promising as a support material in electrocatalysis than a PANI film. Meanwhile, a new application for regular carbon black as a doping material into conducting polymer for electrocatalysis was thus demonstrated. (C) 2005 Elsevier Ltd. All rights reserved.