Tetrametallic D3-symmetric alkoxide molecules containing aluminum

被引：34

作者：

Atwood, DA ^{[1
]}

Jegier, JA

Liu, SM

Rutherford, D

Wei, PR

Tucker, RC

机构：

[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA

[2] Praxair Surface Technol Inc, Indianapolis, IN 46224 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 06期

关键词：

D O I：

10.1021/om980900c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new series of aluminum alkoxide molecules of formula [Al{(mu-OEt)(2)AlR2}(3)], where R Me (1), Et (2),Bu-i (3), and [Al{(mu-OEt)(2)GaR2}(3)], where R = Me (4) and Et (5), have been synthesized and fully characterized. In pure form 1, 2, and 4 are crystalline solids. However, in the presence of a small amount of solvent or impurity all of the compounds exist as oils. They were characterized by H-1 NMR, IR, elemental analysis, mp, and single-crystal X-ray diffractometry for compounds 1, 2, and 4.

引用

页码：976 / 981

页数：6

共 36 条

[1] STRUCTURAL THEORY FOR METAL ALKOXIDE POLYMERS [J].