Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries

被引:858
作者
Elazari, Ran [1 ]
Salitra, Gregory [1 ]
Garsuch, Arnd [2 ]
Panchenko, Alexander [2 ]
Aurbach, Doron [1 ]
机构
[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[2] BASF SE, D-67056 Ludwigshafen, Germany
关键词
sulfur; activated carbon electrodes; lithium sulfur batteries; electrochemistry; POLYSULFIDES; DISCHARGE; COMPOSITE;
D O I
10.1002/adma.201103274
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A route for the preparation of binder-free sulfur-carbon cathodes is developed for lithium sulfur batteries. The method is based on the impregnation of elemental sulfur into the micropores of activated carbon fibers. These electrodes demonstrate good electrochemical performance at high current density attributed to the uniform dispersion of sulfur inside the carbon fiber.
引用
收藏
页码:5641 / +
页数:5
相关论文
共 22 条
[1]   Li/S fundamental chemistry and application to high-performance rechargeable batteries [J].
Akridge, JR ;
Mikhaylik, YV ;
White, N .
SOLID STATE IONICS, 2004, 175 (1-4) :243-245
[2]   On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li-Sulfur Batteries [J].
Aurbach, Doron ;
Pollak, Elad ;
Elazari, Ran ;
Salitra, Gregory ;
Kelley, C. Scordilis ;
Affinito, John .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (08) :A694-A702
[3]   Rechargeable lithium sulfur battery - I. Structural change of sulfur cathode during discharge and charge [J].
Cheon, SE ;
Ko, KS ;
Cho, JH ;
Kim, SW ;
Chin, EY ;
Kim, HT .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (06) :A796-A799
[4]   Morphological and Structural Studies of Composite Sulfur Electrodes upon Cycling by HRTEM, AFM and Raman Spectroscopy [J].
Elazari, Ran ;
Salitra, Gregory ;
Talyosef, Yossi ;
Grinblat, Judith ;
Scordilis-Kelley, Charislea ;
Xiao, Ang ;
Affinito, John ;
Aurbach, Doron .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (10) :A1131-A1138
[5]   COULOMB-GAP MAGNETOTRANSPORT IN GRANULAR AND POROUS CARBON STRUCTURES [J].
FUNG, AWP ;
WANG, ZH ;
DRESSELHAUS, MS ;
DRESSELHAUS, G ;
PEKALA, RW ;
ENDO, M .
PHYSICAL REVIEW B, 1994, 49 (24) :17325-17335
[6]  
GREGG SJ, 1982, ADSORPTION SURFACE A, pCH4
[7]   A High-Performance Polymer Tin Sulfur Lithium Ion Battery [J].
Hassoun, Jusef ;
Scrosati, Bruno .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (13) :2371-2374
[8]   Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries [J].
Jayaprakash, N. ;
Shen, J. ;
Moganty, Surya S. ;
Corona, A. ;
Archer, Lynden A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (26) :5904-5908
[9]   Advances in Li-S batteries [J].
Ji, Xiulei ;
Nazar, Linda F. .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (44) :9821-9826
[10]  
Ji XL, 2009, NAT MATER, V8, P500, DOI [10.1038/NMAT2460, 10.1038/nmat2460]