Heterometallic tetrazole coordination polymer formed through 2+3 cycloaddition reaction between inorganic complexes in the presence of lewis acid

被引：53

作者：

Tang, Yun-Zhi

Wang, Guo-Xi

Ye, Qiong ^{[1
]}

Xiong, Ren-Gen

Yuan, Rong-Xin

机构：

[1] SE Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China

[2] Nanjing Univ, Coordinat Chem Inst, Nanjing 210093, Peoples R China

[3] Changshu Inst Technol, Dept Chem & Mat Engn, Changshu 215500, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2007年 / 7卷 / 12期

关键词：

HUISGEN 1,3-DIPOLAR CYCLOADDITION; BLUE FLUORESCENT EMISSION; CLICK CHEMISTRY APPROACH; PHOTOLUMINESCENCE PROPERTIES; SUPRAMOLECULAR STRUCTURES; DIAMONDOID NETWORKS; BUILDING-BLOCKS; METAL-COMPLEXES; BONDING MODE; LIGAND;

D O I：

10.1021/cg070528g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two in situ 2 + 3 intermolecular cycloaddition reactions between inorganic complexes bis(3-cyanopyrdine)copper(II)azide (A) offer homometallic and heterometallic 3D novel tetrazole coordination polymers, (3-C5H4N-CN4)(2)Cu(I)(2) (1) and (3-C5H4NCN4)Cu(I)Cd(II)Cl-2 (2), respectively, in the presence of Lewis acid CuCl2 and CdC1(2) in which A is used to replace the organic cyano group and NaN3 during Sharpless's tetrazole synthesis. Their interesting luminescent properties are reported.

引用

页码：2382 / 2386

页数：5

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