Neutral metallomacrocycles with four or ten (PEt3)Pd(II) centers

被引:36
作者
Brasey, T [1 ]
Scopelliti, R [1 ]
Severin, K [1 ]
机构
[1] Swiss Fed Inst Technol, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1021/ic048619f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of [(Et3P)PdCl2](2) with 2,3-dihydroxypyridine, 5-chloro-2,3,-dihydroxypyridine, or 2-hydroxynicotinic acid in the presence of base gives neutral, metallomacrocyclic compounds in which the heterocycles act as dianionic, bridging ligands. The macrocycles contain four or ten palladium atoms as evidenced by single crystal X-ray analyses.
引用
收藏
页码:160 / 162
页数:3
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