Luminescent properties of Sr2MgSi2O7 and Ca2MgSi2O7 long lasting phosphors activated by Eu2+, Dy3+

被引:151
作者
Fei, Q [1 ]
Chang, CK [1 ]
Mao, DL [1 ]
机构
[1] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200030, Peoples R China
基金
上海市自然科学基金;
关键词
luminescence; phosphor; alkaline earth silicates; long afterglow;
D O I
10.1016/j.jallcom.2004.06.096
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Long lasting afterglow phosphors Sr2MgSi2O7:Eu,Dy and Ca2MgSi2O7:Eu,Dy were prepared by solid-state reaction method. It is revealed by the results that both phosphors show two emission peaks that are caused by the different emitting centers EU2+ held in the host lattice. Wavelength shift was observed due to the slight differences in the structure parameters of the two hosts. Investigation on afterglow property shows that Sr2MgSi2O7:Eu,Dy phosphor held a better afterglow property than Ca2MgSi2O7:Eu,Dy phosphor. Thermal simulated luminescence study indicates that the long afterglow is generated by a higher trap concentration formed by the co-doped rare earth ions within the host. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:133 / 137
页数:5
相关论文
共 11 条
[1]
FLUORESCENCE OF EU2+-ACTIVATED PHASES IN BINARY ALKALINE EARTH ORTHOSILICATE SYSTEMS [J].
BARRY, TL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1968, 115 (11) :1181-&
[2]
Bindi L, 2001, ACTA CRYSTALLOGR B, V57, P739, DOI 10.1107/SO108768101014495
[3]
Thermally stimulated luminescence from x-irradiated porous silicon [J].
Cooke, DW ;
Bennett, BL ;
Farnum, EH ;
Hults, WL ;
Muenchausen, RE ;
Smith, JL .
APPLIED PHYSICS LETTERS, 1997, 70 (26) :3594-3596
[4]
Trap states of tris-8-(hydroxyquinoline) aluminum and naphthyl-substituted benzidine derivative using thermally stimulated luminescence [J].
Forsythe, EW ;
Morton, DC ;
Tang, CW ;
Gao, YL .
APPLIED PHYSICS LETTERS, 1998, 73 (11) :1457-1459
[5]
Preparation of a new long afterglow blue-emitting Sr2MgSi2O7-based photoluminescent phosphor [J].
Lin, YH ;
Tang, ZL ;
Zhang, ZT ;
Wang, XX ;
Zhang, JY .
JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (16) :1505-1506
[6]
Luminescent properties of a new long afterglow EU2+ and Dy3+ activated Ca3MgSi2O8 phosphor [J].
Lin, YH ;
Zhang, ZT ;
Tang, ZL ;
Wang, XX ;
Zhang, JY ;
Zheng, ZS .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (05) :683-685
[7]
MATASUZAWA T, 1997, J ELECTROCHEM SOC, V144, pL243
[8]
Effect of composition on the phosphorescence from BaAl2O4: Eu2+, Dy3+ crystals [J].
Sakai, R ;
Katsumata, T ;
Komuro, S ;
Morikawa, T .
JOURNAL OF LUMINESCENCE, 1999, 85 (1-3) :149-154
[9]
Transition from the incommensurately modulated structure to the lock-in phase in Co-akermanite [J].
Schaper, AK ;
Schosnig, M ;
Kutoglu, A ;
Treutmann, W ;
Rager, H .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2001, 57 (04) :443-448
[10]
VANUITERT LG, 1984, J LUMIN, V29, P1, DOI 10.1016/0022-2313(84)90036-X