Polysulfurated branched molecules containing functionalized m-phenylene sulfides

被引：82

作者：

Van Bierbeek, A ^{[1
]}

Gingras, M ^{[1
]}

机构：

[1] Free Univ Brussels, Fac Sci, Div Organ Chem, Lab Supramol Chem & Catalysis, B-1050 Brussels, Belgium

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(98)01327-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polysulfurated branched molecules (dendrons) containing functionalized m-phenylene sulfide units were synthesized. An efficient way of making complex aromatic thiols from arylmethylthio groups is shown. A systematic study of the selectivity for producing a new series of phenylene sulfides was achieved. It has lead to the synthesis of rare dendrons containing sulfur and it will open the door to new poly(arylthio) dendrimers. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：6283 / 6286

页数：4

相关论文

共 30 条

[1] THIOETHERS FROM HALOGEN COMPOUNDS AND CUPROUS MERCAPTIDES .2. [J].

ADAMS, R ;

FERRETTI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (18) :4927-4931

[2]

ADAMS R, 1957, CROATIA CHIM ACTA, P29

[3] NOVEL POLYSULFUR BRIDGED METACYCLOPHANES FROM THE IRON-CATALYZED REACTION OF BIS-(2,4-DIMETHOXYPHENYL) SULFIDE WITH DISULFUR DICHLORIDE - EVIDENCE FOR THE CLEAVAGE OF THE CARBON-SULFUR BOND BY ELECTROPHILIC AGENTS [J].

BOTTINO, F ;

PAPPALARDO, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (03) :718-722

[4] SYNTHESIS, H-1-NMR SPECTRAL PROPERTIES AND CONFORMATIONAL PREFERENCES OF SOME OPEN-CHAIN AND CYCLIC AROMATIC SULFIDES CONTAINING PYRIDINE OR 1,3,4-THIADIAZOLE UNITS [J].

BOTTINO, F ;

PAPPALARDO, S .

ORGANIC MAGNETIC RESONANCE, 1981, 16 (01) :1-6

[5] SYNTHESIS AND CHARACTERIZATION OF OXYGEN AND SULFUR BRIDGED AROMATIC MACROCYCLES [J].

BOTTINO, F ;

FOTI, S ;

PAPPALARDO, S .

TETRAHEDRON, 1976, 32 (21) :2567-2570

[6] REACTION OF BROMONAPHTHALENES AND FLUORONAPHTHALENES WITH BUTYL MERCAPTIDE IN DIMETHYL SULFOXIDE [J].

BRADSHAW, JS ;

SOUTH, JA ;

HALES, RH .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (15) :2381-&

[7]

Campbell J. R., 1964, J ORG CHEM, V29, P1830

[8] NUCLEOPHILIC AROMATIC-SUBSTITUTION REACTIONS OF CHLOROANILINES AND CHLOROANILIDES WITH POTASSIUM PHENYL THIOLATE [J].

CARUSO, AJ ;

COLLEY, AM ;

BRYANT, GL .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (02) :862-865

[9] Synthesis of a series of focally-substituted organothiol dendrons [J].

Chen, KY ;

Gorman, CB .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (26) :9229-9235

[10] NUCLEOPHILIC AROMATIC-SUBSTITUTION REACTIONS OF UNACTIVATED ARYL HALIDES WITH THIOLATE IONS IN HEXAMETHYLPHOSPHORAMIDE [J].

COGOLLI, P ;

MAIOLO, F ;

TESTAFERRI, L ;

TINGOLI, M ;

TIECCO, M .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (15) :2642-2646