Flexible dye-sensitized solar cells using ZnO coated TiO2 nanoparticles

被引:108
作者
Kim, SS [1 ]
Yum, JH [1 ]
Sung, YE [1 ]
机构
[1] GIST, Dept Mat Sci & Engn, Kwangju 500712, South Korea
关键词
flexible dye-sensitized solar cell; inherent energy barrier; ZnO layer; recombination;
D O I
10.1016/j.jphotochem.2004.10.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A photoelectrode using ZnO coated TiO2 nanoparticles was prepared for use in flexible dye-sensitized solar cells. To provide an inherent energy barrier between the electrode and electrolyte interface, the surface of the TiO2 nanoparticles was modified by thin ZnO layer. X-ray photoelectron spectroscopy and transmission electron microscopy image confirmed the formation of ZnO with a thickness of ca. similar to 0.5 run, possible thickness for tunneling process in particle-to-particle transport of electrons, on the TiO2 surface. The overall conversion efficiency was increased from 0.71 to 1.21% under a light intensity of 20 mW/cm(2) (0.2 sun) due to the reduced recombination of photoinjected electrons without any post-treatment. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:269 / 273
页数:5
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