Bidentate ligands formed by self-assembly

被引：102

作者：

Slagt, VF ^{[1
]}

van Leeuwen, PWNM ^{[1
]}

Reek, JNH ^{[1
]}

机构：

[1] Univ Amsterdam, Inst Mol Chem, Amsterdam, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 19期

关键词：

D O I：

10.1039/b306683e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel supramolecular strategy to prepare bidentate ligands via the assembly of functionalised monomeric ligands on a dimeric zinc(II) porphyrin template is presented; the assembled bidentate ligands show chelating behaviour and their rhodium complexes display enhanced selectivity in the hydroformylation compared to the non-template analogue.

引用

收藏

页码：2474 / 2475

页数：2

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