Long-lived charge-separated state produced by photoinduced electron transfer in a zinc imidazoporphyrin-C60 dyad

被引：95

作者：

Kashiwagi, Y

Ohkubo, K

McDonald, JA

Blake, IM

Crossley, MJ

Araki, Y

Ito, O

Imahori, H

Fukuzumi, S

机构：

[1] Osaka Univ, CREST, Japan Sci & Technol Corp, Grad Sch Engn,Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[3] Tohoku Univ, CREST, JST, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan

[4] Kyoto Univ, PRESTO, JST, Dept Mol Engn,Grad Sch Engn,Nishigyo Ku, Kyoto 6158510, Japan

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 15期

关键词：

D O I：

10.1021/ol0349256

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photoexcitation of a zinc imidazoporphyrin-fullerene dyad with a short linkage results in formation of the charge-separated state by photoinduced electron transfer. The charge-separated state has a lifetime of 310 mus in benzonitrile at 278 K, which is the longest lifetime in solution ever reported for electron donor-acceptor-linked dyads.

引用

页码：2719 / 2721

页数：3

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