Pulsed laser deposited hard TiC, ZrC, HfC and TaC films on titanium: Hardness and an energy-dispersive X-ray diffraction study

被引:60
作者
Ferro, D. [2 ]
Rau, J. V. [2 ]
Albertini, V. Rossi [3 ]
Generosi, A. [3 ]
Teghil, R. [4 ]
Barinov, S. M. [1 ]
机构
[1] Russian Acad Sci, Inst Phys Chem Ceram, Moscow 119361, Russia
[2] Ist Studio Mat Nanostrutturati, CNR, I-00185 Rome, Italy
[3] Ist Struttura Mat, CNR, I-00133 Rome, Italy
[4] Univ Basilicata, I-85100 Potenza, Italy
关键词
thin films; carbides; pulse laser ablation deposition; X-ray diffraction; hardness;
D O I
10.1016/j.surfcoat.2007.06.060
中图分类号
TB3 [工程材料学];
学科分类号
0805 [材料科学与工程]; 080502 [材料学];
摘要
Thin films of TiC, ZrC, HfC and TAC were pulsed laser ablation deposited onto sandblasted pure titanium substrate at a laser beam fluence of 3 J/cm(2). Deposition temperature was room temperature or 500 degrees C. The films were investigated by scanning electron microscopy, energy-dispersive X-ray diffraction (EDXD) and hardness measurements. The smooth and compact films of 200 to 600 nm thickness were obtained, consisting of tens nanometer particles. The rocking curve EDXD analysis revealed the films are textured. Intrinsic hardness of the films decreases generally with an increase in substrate temperature and in molecular weight of carbides. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1455 / 1461
页数:7
相关论文
共 29 条
[1]
Andrievski R.A., 1989, Strength of Refractory Compounds
[2]
Hardness of hafnium carbide films deposited on silicon by pulsed laser ablation [J].
Barinov, SM ;
Ferro, D ;
Bartuli, C ;
D'Alessio, L .
JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (16) :1485-1487
[3]
The deposition of NbN and NbC thin films by filtered vacuum cathodic arc deposition [J].
Bendavid, A ;
Martin, PJ ;
Kinder, TJ ;
Preston, EW .
SURFACE & COATINGS TECHNOLOGY, 2003, 163 :347-352
[4]
Effect of titanium carbide coating on the osseointegration response in vitro and in vivo [J].
Brama, Marina ;
Rhodes, Nicholas ;
Hunt, John ;
Ricci, Andrea ;
Teghil, Roberto ;
Migliaccio, Silvia ;
Della Rocca, Carlo ;
Leccisotti, Silvia ;
Lioi, Attilio ;
Scandurra, Marta ;
De Maria, Giovanni ;
Ferro, Daniela ;
Pu, Fanrong ;
Panzini, Gianluca ;
Politi, Laura ;
Scandurra, Roberto .
BIOMATERIALS, 2007, 28 (04) :595-608
[5]
The kinetics of phase transitions observed by energy-dispersive X-ray diffraction [J].
Caminiti, R ;
Albertini, VR .
INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 1999, 18 (02) :263-299
[6]
Hardness of titanium carbide films deposited on silicon by pulsed laser ablation [J].
De Maria, G ;
Ferro, D ;
D'Alessio, L ;
Teghil, R ;
Barinov, SM .
JOURNAL OF MATERIALS SCIENCE, 2001, 36 (04) :929-935
[7]
Dissolution behavior of plasma-sprayed hydroxyapatite coatings [J].
Fazan, F ;
Marquis, PM .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2000, 11 (12) :787-792
[8]
Hardness of electron beam deposited titanium carbide films on titanium substrate [J].
Ferro, D ;
Scandurra, R ;
Latini, A ;
Rau, JV ;
Barinov, SM .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (01) :329-330
[9]
Vickers and Knoop hardness of electron beam deposited ZrC and HfC thin films on titanium [J].
Ferro, D ;
Barinov, SM ;
Rau, JV ;
Latini, A ;
Scandurra, R ;
Brunetti, B .
SURFACE & COATINGS TECHNOLOGY, 2006, 200 (16-17) :4701-4707
[10]
Thickness-dependent hardness of pulsed laser ablation deposited thin films of refractory carbides [J].
Ferro, D ;
Teghil, R ;
Barinov, SM ;
D'Alessio, L ;
DeMaria, G .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 87 (2-3) :233-236