Synthesis of Gold Nano-hexapods with Controllable Arm Lengths and Their Tunable Optical Properties

被引:82
作者
Kim, Do Youb [1 ,2 ]
Yu, Taekyung [1 ]
Cho, Eun Chul [1 ]
Ma, Yanyun [1 ]
Park, O. Ok [2 ]
Xia, Younan [1 ]
机构
[1] Washington Univ, Dept Biomed Engn, St Louis, MO 63130 USA
[2] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Grad Program BK21, Taejon 305701, South Korea
关键词
gold; hexapods; nanocrystals; nanostructures; seeded growth; HIGH-YIELD SYNTHESIS; METAL NANOCRYSTALS; DIFFERENT SHAPES; NANOPARTICLES; NANOSTARS; CHEMISTRY; SIZE; OCTAHEDRA; CATALYSIS; BIOLOGY;
D O I
10.1002/anie.201100983
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A star in the making: Gold nano-hexapods with controlled arm lengths were synthesized by selective growth on the vertices of octahedral Au seeds. Depending on the arm length, their surface plasmon resonance peaks shifted from the visible to the near-infrared region (see picture), which could be readily controlled by varying the amount of HAuCl4, the reaction temperature, or both. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:6328 / 6331
页数:4
相关论文
共 30 条
[1]   Tuning Size and Sensing Properties in Colloidal Gold Nanostars [J].
Barbosa, Silvia ;
Agrawal, Amit ;
Rodriguez-Lorenzo, Laura ;
Pastoriza-Santos, Isabel ;
Alvarez-Puebla, Raman A. ;
Kornowski, Andreas ;
Weller, Horst ;
Liz-Marzan, Luis M. .
LANGMUIR, 2010, 26 (18) :14943-14950
[2]   Gold nanoparticles in nanomedicine: preparations, imaging, diagnostics, therapies and toxicity [J].
Boisselier, Elodie ;
Astruc, Didier .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (06) :1759-1782
[3]   Chemistry and properties of nanocrystals of different shapes [J].
Burda, C ;
Chen, XB ;
Narayanan, R ;
El-Sayed, MA .
CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102
[4]   Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].
Daniel, MC ;
Astruc, D .
CHEMICAL REVIEWS, 2004, 104 (01) :293-346
[5]   Surface-enhanced Raman scattering spectroscopy via gold nanostars [J].
Esenturk, E. Nalbant ;
Walker, A. R. Hight .
JOURNAL OF RAMAN SPECTROSCOPY, 2009, 40 (01) :86-91
[6]   Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes [J].
Eustis, S ;
El-Sayed, MA .
CHEMICAL SOCIETY REVIEWS, 2006, 35 (03) :209-217
[7]   Stacking faults in formation of silver nanodisks [J].
Germain, V ;
Li, J ;
Ingert, D ;
Wang, ZL ;
Pileni, MP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (34) :8717-8720
[8]  
Giljohann D.A., 2010, Angew. Chem, V122, P3352, DOI DOI 10.1002/ANGE.200904359
[9]   Gold Nanoparticles for Biology and Medicine [J].
Giljohann, David A. ;
Seferos, Dwight S. ;
Daniel, Weston L. ;
Massich, Matthew D. ;
Patel, Pinal C. ;
Mirkin, Chad A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (19) :3280-3294
[10]   Shape control in gold nanoparticle synthesis [J].
Grzelczak, Marek ;
Perez-Juste, Jorge ;
Mulvaney, Paul ;
Liz-Marzan, Luis M. .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (09) :1783-1791