Fine tuning between organic and inorganic host structure:: new trends in layered double hydroxide hybrid assemblies

被引:302
作者
Leroux, F [1 ]
Taviot-Guého, C [1 ]
机构
[1] Univ Clermont Ferrand, CNRS, Lab Mat Inorgan, UMR 6002, F-63177 Clermont Ferrand, France
关键词
D O I
10.1039/b505014f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Driven by the scientific challenges involved in the creation of nanostructures providing access to new materials with unusual properties, the study of hybrid materials based on Layered Double Hydroxides (LDHs) has developed considerably during the last decade. This feature article is intended to give a broad overview of organic-inorganic hybrid assemblies based on LDH materials including their synthesis and characterization, and pointing out their potential applications. The LDH interlayer gap supplies an interesting, constrained environment arising from the anisotropic accommodation of the guest molecule at the nanoscale. Particularly, this article underlines the importance of compatibility between the two components, i.e. the organic and inorganic parts, in terms of charge distribution and molecular size for the polymerization process of interleaved molecules. Exfoliation and staging phenomena are also described. Through several examples of the shape and function of interlayer organic anions, hybrid LDH materials are described for their potential properties in optic devices, as drug delivery systems, and also as nano- and macro-fillers in polymer nanocomposites and cements, respectively. Eventually, LDH hybrid materials merge into even more complex systems for which topical applications are listed.
引用
收藏
页码:3628 / 3642
页数:15
相关论文
共 142 条
[91]   INTERCALATION POLYMERIZATION OF THE ANILINIUM CATION IN THE VOPO4 INTERLAYER SPACE [J].
NAKAJIMA, H ;
MATSUBAYASHI, G .
CHEMISTRY LETTERS, 1993, (03) :423-426
[92]   SYNTHESIS AND PROPERTIES OF NOVEL WATER-SOLUBLE CONDUCTING POLYANILINE COPOLYMERS [J].
NGUYEN, MT ;
KASAI, P ;
MILLER, JL ;
DIAZ, AF .
MACROMOLECULES, 1994, 27 (13) :3625-3631
[93]   Time-resolved, in situ X-ray diffraction studies of intercalation in lamellar hosts [J].
O'Hare, D ;
Evans, JSO ;
Fogg, A ;
O'Brien, S .
POLYHEDRON, 2000, 19 (03) :297-305
[94]   Delamination of layered double hydroxides in polar monomers: new LDH-acrylate nanocomposites [J].
O'Leary, S ;
O'Hare, D ;
Seeley, G .
CHEMICAL COMMUNICATIONS, 2002, (14) :1506-1507
[95]   PHOTOFUNCTIONS OF INTERCALATION COMPOUNDS [J].
OGAWA, M ;
KURODA, K .
CHEMICAL REVIEWS, 1995, 95 (02) :399-438
[96]   Incorporation of poly(acrylic acid), poly(vinylsulfonate) and poly(styrenesulfonate) within layered double hydroxides [J].
Oriakhi, CO ;
Farr, IV ;
Lerner, MM .
JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (01) :103-107
[97]   Thermal characterization of poly(styrene sulfonate) layered double hydroxide nanocomposites [J].
Oriakhi, CO ;
Farr, IV ;
Lerner, MM .
CLAYS AND CLAY MINERALS, 1997, 45 (02) :194-202
[98]  
Pinnavia T.J., 2000, POLYM CLAY NANOCOMPO
[99]   Staging of organic and inorganic anions in layered double hydroxides [J].
Pisson, J ;
Taviot-Guého, C ;
Israëli, Y ;
Leroux, F ;
Munsch, P ;
Itié, JP ;
Briois, V ;
Morel-Desrosiers, N ;
Besse, JP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (35) :9243-9248
[100]   SORPTION PROPERTIES OF CARBON COMPOSITE-MATERIALS FORMED FROM LAYERED CLAY-MINERALS [J].
PUTYERA, K ;
BANDOSZ, TJ ;
JAGIELLO, J ;
SCHWARZ, JA .
CLAYS AND CLAY MINERALS, 1994, 42 (01) :1-6