Quantitative analysis of trace metal ions in ice using laser-induced breakdown spectroscopy

被引：125

作者：

Cáceres, JO ^{[1
]}

López, JT ^{[1
]}

Telle, HH ^{[1
]}

Ureña, AG ^{[1
]}

机构：

[1] Univ Complutense Madrid, Unidad Lasers & Haces Mol, Inst Pluridisciplinar, Madrid 28040, Spain

来源：

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 2001年 / 56卷 / 06期

关键词：

trace metal analysis; liquid analysis; laser breakdown spectroscopy;

D O I：

10.1016/S0584-8547(01)00173-2

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

This work reports on a simple, quick-freeze method for the quantitative analysis of trace metal ions in liquids applying the laser-induced breakdown spectroscopy (LIBS) technique. Using this procedure with calibrated samples, well-characterized linear working curves were determined for Na and Al water solutions over the 0.01-1% concentration range. This allowed detection limits of the order of ppm. In addition, optimum experimental conditions were found that allow the analysis to be carried out in a fast and very easy manner, without the limitations and difficulties found with liquid samples. The advantages of this simple and direct method, developed and patented by the Instituto Pluridisciplinar-UCM, are discussed, and potential applications for industrial analysis are also suggested. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：831 / 838

页数：8

共 26 条

[11] ERBIUM LASER ABLATION - THE EFFECT OF DYNAMIC OPTICAL-PROPERTIES
CUMMINGS, JP
WALSH, JT
[J]. APPLIED PHYSICS LETTERS, 1993, 62 (16) : 1988 - 1990
[12] Characterization of colloidal particles by laser-induced plasma spectroscopy (LIPS)
Haisch, C
Liermann, J
Panne, U
Niessner, R
[J]. ANALYTICA CHIMICA ACTA, 1997, 346 (01) : 23 - 35
[13] Spectrochemical analysis of liquids using laser-induced plasma emissions: Effects of laser wavelength
Ho, WF
Ng, CW
Cheung, NH
[J]. APPLIED SPECTROSCOPY, 1997, 51 (01) : 87 - 91
[14] DETERMINATION OF COLLOIDAL IRON IN WATER BY LASER-INDUCED BREAKDOWN SPECTROSCOPY
ITO, Y
UEKI, O
NAKAMURA, S
[J]. ANALYTICA CHIMICA ACTA, 1995, 299 (03) : 401 - 405
[15] Laser induced breakdown spectroscopy (LIBS) as an analytical tool for the detection of metal ions in aqueous solutions
Knopp, R
Scherbaum, FJ
Kim, JI
[J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1996, 355 (01): : 16 - 20
[16] LIMIT OF DETECTION
LONG, GL
WINEFORDNER, JD
[J]. ANALYTICAL CHEMISTRY, 1983, 55 (07) : A712 - +
[17] LOREE TR, 1981, P SOC PHOTO-OPT INST, V288, P241, DOI 10.1117/12.932049
[18] LOREE TR, 1981, J PLASMA CHEM PLASMA, V1, P271
[19] Spectrochemical analysis of liquids using laser-induced plasma emissions: Effects of laser wavelength on plasma properties
Ng, CW
Ho, WF
Cheung, NH
[J]. APPLIED SPECTROSCOPY, 1997, 51 (07) : 976 - 983
[20] DOUBLE-PULSE TECHNIQUE FOR OPTICAL-EMISSION SPECTROSCOPY OF ABLATION PLASMAS OF SAMPLES IN LIQUIDS
NYGA, R
NEU, W
[J]. OPTICS LETTERS, 1993, 18 (09) : 747 - 749

← 1 2 3 →