Introduction to chiral crystallization of achiral organic compounds spontaneous generation of chirality

被引：163

作者：

Matsuura, T ^{[1
]}

Koshima, H ^{[1
]}

机构：

[1] Ehime Univ, Fac Engn, Dept Appl Chem, Matsuyama, Ehime 7908577, Japan

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS | 2005年 / 6卷 / 01期

关键词：

chiral crystallization; achiral organic compounds; chiral crystals; chirality generation; spontaneous resolution; enantiomorphic crystals; x-ray crystallographic analysis; chiral space group; Cambridge structural database; optical activity;

D O I：

10.1016/j.jphotochemrev.2005.02.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chiral crystallization of optically inactive (achiral) compounds has not been a commonly known phenomenon in organic chemistry. However, large numbers of achiral compounds such as benzophenone, phenol, phenanthrene, etc. are known to crystallize into chiral crystals from their solutions. This review deals with the general aspects of this phenomenon: what is chiral crystallization, how to find organic compounds undergoing chiral crystallization, the preparation of chiral crystals from achiral organic compounds, and the generation of chirality. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：7 / 24

页数：18

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