Ion multivalence and like-charge polyelectrolyte attraction

被引:175
作者
Butler, JC
Angelini, T
Tang, JX
Wong, GCL
机构
[1] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA
[2] Univ Illinois, Dept Phys, Urbana, IL 61801 USA
[3] Univ Illinois, Dept Bioengn, Urbana, IL 61801 USA
[4] Brown Univ, Dept Phys, Providence, RI 02912 USA
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevLett.91.028301
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
It is known empirically that multivalent ions generate attractions between like-charged polyelectrolytes, with different valence requirements for different systems. How multivalent must an ion be before it can condense a given polyelectrolyte? Using charge-tunable M13 virus rods and a family of artificial homologous "dumbbell" divalent ions of different sizes, we have constructed a multivalent ion-polyelectrolyte phase diagram, and find an experimentally motivated general criterion for like-charged attraction based on the ion valence, ion size, and the Gouy-Chapman length.
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页数:4
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