A neutral, water-soluble olefin metathesis catalyst based on an N-heterocyclic carbene ligand

被引：159

作者：

Gallivan, JP ^{[1
]}

Jordan, JP ^{[1
]}

Grubbs, RH ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Lab Chem Synth, Pasadena, CA 91125 USA

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 15期

基金：

美国国家卫生研究院;

关键词：

olefin metathesis; aqueous metathesis; ruthenium; N-heterocyclic carbene; ring-opening metathesis polymerization;

D O I：

10.1016/j.tetlet.2005.02.096

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A water-soluble ruthenium-based olefin metathesis catalyst supported by a poly(ethylene glycol) conjugated N-heterocyclic carbene ligand is reported. The catalyst displays greater activity in aqueous ring-opening metathesis polymerization (ROMP) reactions than previously reported water-soluble metathesis catalysts. (c) 2005 Published by Elsevier Ltd.

引用

页码：2577 / 2580

页数：4

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