Palladium-catalyzed asymmetric reduction of allylic esters with a new chiral monodentate ligand, 8-diphenylphosphino-8′-methoxy-1,1′-binaphthyl

被引：39

作者：

Fuji, K ^{[1
]}

Sakurai, M

Kinoshita, T

Kawabata, T

机构：

[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 611, Japan

[2] Fujisawa Pharmaceut Co Ltd, Chem Res Labs, Yodogawa Ku, Osaka 532, Japan

[3] Fujisawa Pharmaceut Co Ltd, Basic Res Labs, Yodogawa Ku, Osaka 532, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 35期

关键词：

asymmetric reactions; hydrogenolysis; phosphines; palladium and compounds;

D O I：

10.1016/S0040-4039(98)01342-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new chiral monodentate ligand, 8-diphenylphosphino-8'-methoxy-1,1'-binaphthyl (8-MeO-MOP), was used for palladium-catalyzed reduction of allylic carbonates with formic acid. Various methylcarbonates of 3,3'-disubstituted allylic alcohols were converted to the corresponding optically active 1-olefins with this ligand. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：6323 / 6326

页数：4

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