Synthesis and structure of a tetranuclear niobium telluride cuboidal cluster with a central μ4-O ligand

被引：25

作者：

Fedin, VP

Kalinina, IV

Virovets, AV

Podberezskaya, NV

Neretin, IS

Slovokhotov, YL

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 23期

关键词：

D O I：

10.1039/a805956j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-temperature reaction of NbTe4 with KCN at 450 degrees C and further crystallization from aqueous solution produces an oxygen-centered tetranuclear niobium cubane-type complex, isolated here as K-6[Nb4OTe4(CN)(12)]. K2CO3. KOH . 8H(2)O, and characterized by X-ray crystallography.

引用

收藏

页码：2579 / 2580

页数：2

相关论文

共 31 条

[1] SYNTHESIS AND STRUCTURE OF TA4SITE4, A NEW LOW-DIMENSIONAL MATERIAL [J].

BADDING, ME ;

DISALVO, FJ .

INORGANIC CHEMISTRY, 1990, 29 (20) :3952-3954

[2] CU40 (AMINE)4(HALO)6 COPPER COMPLEXES WITH TETRAHEDRALLY COORDINATED OXYGEN [J].

BOCK, H ;

DIECK, HT ;

PYTTLIK, H ;

SCHNOLLE.M .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1968, 357 (1-2) :54-&

[3] Diverse solid-state clusters with strong metal-metal bonding. In praise of synthesis [J].

Corbett, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (05) :575-587

[4] AN OXYGEN-CENTERED TETRANUCLEAR TITANIUM COMPOUND TI4O(S2)4CL6 [J].

COTTON, FA ;

FENG, XJ ;

KIBALA, PA ;

SANDOR, RBW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) :2148-2151

[5] NEW NIOBIUM COMPLEXES WITH ALKYNES .4. A COMPOUND CONTAINING BOTH AN OXO-CENTERED TETRAMERIC ANION AND A RELATED DINUCLEAR CATION [J].

COTTON, FA ;

SHANG, MY .

INORGANIC CHEMISTRY, 1990, 29 (14) :2619-2622

[6] METAL CHALCOGENIDE CLUSTER CHEMISTRY [J].

DANCE, I ;

FISHER, K .

PROGRESS IN INORGANIC CHEMISTRY, VOL 41, 1994, 41 :637-803

[7] First complexes with cuboidal-type M4Te4 (M=Mo, W) cluster cores:: synthesis and structure of K7[Mo4(μ3-Te)4(CN)12]•11H2O and K6[W4(μ3-Te)4(CN)12]•5H2O [J].

Fedin, VP ;

Kalinina, IV ;

Virovets, AV ;

Podberezskaya, NV ;

Sykes, AG .

CHEMICAL COMMUNICATIONS, 1998, (02) :237-238

[8]

FEDIN VP, UNPUB

[9]

Fedorov V. E., 1985, RUSS CHEM REV, V54, P408, DOI DOI 10.1070/RC1985V054N04ABEH003064

[10] STRUCTURE, BONDING AND ELECTRON COUNTS IN CUBANE-TYPE CLUSTERS HAVING M4S4, M2M2'S4 AND MM3'S4 CORES [J].

HARRIS, S .

POLYHEDRON, 1989, 8 (24) :2843-2882

← 1 2 3 4 →