First complexes with cuboidal-type M4Te4 (M=Mo, W) cluster cores:: synthesis and structure of K7[Mo4(μ3-Te)4(CN)12]•11H2O and K6[W4(μ3-Te)4(CN)12]•5H2O

被引：31

作者：

Fedin, VP

Kalinina, IV

Virovets, AV

Podberezskaya, NV

Sykes, AG

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 02期

关键词：

D O I：

10.1039/a707995h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-temperature reactions of MO3Te7I4 Or WTe2 with KCN at 450 degrees C produce M4Te4 cubane-type complexes, isolated here as K-7[Mo-4(mu(3)-Te)(4)(CN)(12)].11H(2)O and K-6[W-4(mu(3)-Te)(4)(CN)(12)].5H(2)O in high yields, and characterized by X-ray crystallography.

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页码：237 / 238

页数：2

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