Ultracentrifugation of single-walled nanotubes

被引:60
作者
Green, Alexander A. [1 ]
Hersam, Mark C. [1 ]
机构
[1] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
基金
加拿大自然科学与工程研究理事会; 美国国家科学基金会;
关键词
D O I
10.1016/S1369-7021(07)70309-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Singie-walled carbon nanotubes (SWNTs) are high aspect ratio cylinders of carbon (similar to 1 nm in diameter) whose walls are one atomic layer thick and have an atomic arrangement analogous to graphite. The SWNT atomic structure is defined by a two-dimensional chiral vector whose components are specified by a pair of positive integers: (n,m). This chiratity of the SWNT dictates its properties. Unfortunately, current methods for producing SWNTs lack control over chirality, leading to significant polydispersity in the properties of as-synthesized SWNTs. Consequently, the widespread use of SWNTs in electronics, photonics, and sensors has been limited by their inhomogeneity.
引用
收藏
页码:59 / 60
页数:2
相关论文
共 13 条
[1]   Sorting carbon nanotubes by electronic structure using density differentiation [J].
Arnold, Michael S. ;
Green, Alexander A. ;
Hulvat, James F. ;
Stupp, Samuel I. ;
Hersam, Mark C. .
NATURE NANOTECHNOLOGY, 2006, 1 (01) :60-65
[2]   Enrichment of single-walled carbon nanotubes by diameter in density gradients [J].
Arnold, MS ;
Stupp, SI ;
Hersam, MC .
NANO LETTERS, 2005, 5 (04) :713-718
[3]   Engineering carbon nanotubes and nanotube circuits using electrical breakdown [J].
Collins, PC ;
Arnold, MS ;
Avouris, P .
SCIENCE, 2001, 292 (5517) :706-709
[4]   Quantum yield heterogeneities of aqueous single-wall carbon nanotube suspensions [J].
Crochet, Jared ;
Clemens, Michael ;
Hertel, Tobias .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8058-+
[5]  
Foley ET, 2006, NANOTECHNOL LAW BUS, V3, P467
[6]  
Graham J., 2001, BIOL CENTRIFUGATION
[7]   Controlled production of single-wall carbon nanotubes by catalytic decomposition of CO on bimetallic Co-Mo catalysts [J].
Kitiyanan, B ;
Alvarez, WE ;
Harwell, JH ;
Resasco, DE .
CHEMICAL PHYSICS LETTERS, 2000, 317 (3-5) :497-503
[8]   Separation of metallic from semiconducting single-walled carbon nanotubes [J].
Krupke, R ;
Hennrich, F ;
von Löhneysen, H ;
Kappes, MM .
SCIENCE, 2003, 301 (5631) :344-347
[9]   Electronic structure control of single-walled carbon nanotube functionalization [J].
Strano, MS ;
Dyke, CA ;
Usrey, ML ;
Barone, PW ;
Allen, MJ ;
Shan, HW ;
Kittrell, C ;
Hauge, RH ;
Tour, JM ;
Smalley, RE .
SCIENCE, 2003, 301 (5639) :1519-1522
[10]   Selective etching of metallic carbon nanotubes by gas-phase reaction [J].
Zhang, Guangyu ;
Qi, Pengfei ;
Wang, Xinran ;
Lu, Yuerui ;
Li, Xiaolin ;
Tu, Ryan ;
Bangsaruntip, Sarunya ;
Mann, David ;
Zhang, Li ;
Dai, Hongjie .
SCIENCE, 2006, 314 (5801) :974-977