The complementary use of radioanalytical methods and trace analysis methods for the characterisation of environmental IAEA reference materials

被引:1
作者
De Regge, P [1 ]
Burns, K [1 ]
Campbell, M [1 ]
Makarewicz, M [1 ]
Markowicz, A [1 ]
Mattiuzzi, M [1 ]
Tajani, A [1 ]
Toervenyi, A [1 ]
Zeiller, E [1 ]
机构
[1] Int Atom Energy Agcy, Seibersdorf Labs, A-1400 Vienna, Austria
关键词
IAEA; INAA; Trace Element Concentration; Trace Analysis; Trace Element Content;
D O I
10.1023/A:1010683604343
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The IAEA laboratories have access to both nuclear analytical methods and conventional instrumental methods for trace analysis for the characterisation of its environmental and biological reference materials. A technical concept integrating the homogeneity data, the recommended test portion mass and the uncertainty on the trace element concentrations is explored using a combination of INAA, XRF, ICP-MS, ICP-AES, and AAS. The above approach is illustrated by selected examples of reference materials currently under evaluation for their trace element content. They include some or all of the following elements Al, As, Br, Ca, Cd, Co, Cr, Cs, Cu, Fe, Hg; K, Mg, Mn, Mo, Na, Ni, Pb, Rb, Se, Sr, Th, U, Zn in environmental biomonitor organisms (lichen, algae) and air dust filters.
引用
收藏
页码:217 / 225
页数:9
相关论文
共 8 条
[1]   APPLICATIONS OF A CAPILLARY BASED X-RAY MICROFLUORESCENCE SYSTEM [J].
BERNASCONI, G ;
HASELBERGER, N ;
MARKOWICZ, A ;
VALKOVIC, V .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1994, 86 (3-4) :333-338
[2]  
HORWITZ B, 1982, ANAL CHEM, V54, pA67
[3]  
*IAEA, 1999, IAEAAL079
[4]   PROPOSED SAMPLING CONSTANT FOR USE IN GEOCHEMICAL ANALYSIS [J].
INGAMELLS, CO ;
SWITZER, P .
TALANTA, 1973, 20 (06) :547-568
[5]  
*ISO, 1999, 34 ISO
[6]  
*ISO, 1989, 35 ISO
[7]  
MATTIUZZI M, 1999, 48 ANN DENV XRAY C S
[8]   DETERMINATION OF THE MINIMUM SAMPLE MASS OF A SOLID CRM TO BE USED IN CHEMICAL-ANALYSIS [J].
PAUWELS, J ;
VANDECASTEELE, C .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1993, 345 (2-4) :121-123