Synthesis and crystal structure of an unsymmetric gadolinium(III) cryptate

被引：4

作者：

Chen, QY ^{[1
]}

Luo, QH ^{[1
]}

Liu, YJ ^{[1
]}

Duan, CY ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2000年 / 30卷 / 03期

基金：

中国国家自然科学基金;

关键词：

gadolinium(III) cryptate; macrocyclic ligands; Schiff-base;

D O I：

10.1023/A:1009578930404

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The synthesis and crystal and molecular structure of [Gd(H3L)(NO3)(H2O)](ClO4)(2) are reported. The complex crystallizes in the orthorhombic system, space group Pbca with lattice parameters a = 16.974(8), b = 20.010(4), c = 25.202(4) Angstrom, and D-calc = 1.736 mg m(-3), for Z = 8. The coordination number of gadolinium (III) is nine, and its coordination geometry is a distorted monocapped square antiprisms. In the complex, three benzene rings make dihedral angles of 91.7, 92.7, 66.3 degrees, respectively. A water molecule acts as a guest molecule encapsulated in the cryptate.

引用

页码：177 / 180

页数：4

共 15 条

[1] DESIGN AND SYNTHESIS OF MACROCYCLIC LIGANDS AND THEIR COMPLEXES OF LANTHANIDES AND ACTINIDES [J].

ALEXANDER, V .

CHEMICAL REVIEWS, 1995, 95 (02) :273-342

[2]

[Anonymous], 1995, SHELXTL VERS 5 0 REF

[3] Metal template synthesis of lanthanide cryptates. Crystal structure of a dysprosium cryptate [J].

Avecilla, F ;

Bastida, R ;

deBlas, A ;

Fenton, DE ;

Macias, A ;

Rodriguez, A ;

RodriguezBlas, T ;

GarciaGranda, S ;

CorzoSuarez, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (03) :409-413

[4]

Bunzli J.C.G., 1989, CHEM EARTH SCI THEOR

[5] KINETICALLY STABLE LANTHANIDE CRYPTATES [J].

DREW, MGB ;

HOWARTH, OW ;

HARDING, CJ ;

MARTIN, N ;

NELSON, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (08) :903-905

[6] Synthesis and crystal structural characterization of an unsymmetric neodymium(III) cryptate [J].

Feng, CJ ;

Luo, QH ;

Duan, CY ;

Shen, MC ;

Liu, YJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (08) :1377-1380

[7]

KIMURA E, 1970, INORG CHEM, V9, P118

[8] PERSPECTIVES IN SUPRAMOLECULAR CHEMISTRY - FROM MOLECULAR RECOGNITION TOWARDS MOLECULAR INFORMATION-PROCESSING AND SELF-ORGANIZATION [J].

LEHN, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (11) :1304-1319

[9] IMPLEMENTATION OF MACROCYCLE CONJUGATED ANTIBODIES FOR TUMOR-TARGETING [J].

PARKER, D ;

MORPHY, JR ;

JANKOWSKI, K ;

COX, J .

PURE AND APPLIED CHEMISTRY, 1989, 61 (09) :1637-1641

[10] Getting excited about lanthanide complexation chemistry [J].

Parker, D ;

Williams, JAG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (18) :3613-3628

← 1 2 →