Effects of strained bicyclic annelation on the benzene nucleus: The X-ray crystal structures of a triphenylene and two anthracene derivatives

被引：26

作者：

Cardullo, F

Giuffrida, D

Kohnke, FH

Raymo, FM

Stoddart, JF

Williams, DJ

机构：

[1] UNIV MESSINA,DIPARTIMENTO CHIM ORGAN & BIOL,I-98166 MESSINA,ITALY

[2] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

[3] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1996年 / 35卷 / 03期

关键词：

bond-length alternation; Mills-Nixon effect; polycycles; strained rings; triepoxytriphenylenes;

D O I：

10.1002/anie.199603391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pronounced bond length alternation in the central aromatic ring is the eye-catching structural feature of triepoxytriphenylene 1. By contrast, no significant bond length alternation is observed in the linearly bisannelated compounds 2 and 3. The key difference is ascribed to the position of annelations with the bicyclic units (Image Presented). © 1996, Wiley-VCH Verlag. All rights reserved.

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页码：339 / 341

页数：3

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